This is one of the most confusing issue for many folks. According to Freightliner, the correct pressure for tires is found by having the rig weighed on each corner to determine several things.
1: the load is properly distributed side to side
2: the total weight per axel is not exceeded
3: it allows you to view the tire manufacturers charts to determine the proper inflation rate for your tires.
the heaviest weight per axel is the load weight used to determine what the PSI should be for that axel. All tires on an axel are inflated to the same PSI. As a rule, if the chart says 90PSI I would inflate to 95PSI to allow for changes.
Hope that helps